I feel like I need to point out that these Avengers looks aren't based on the characters' makeup, but inspired by their color scheme and personality.
That being said, this look is based on the outfit, hair color and bad-assery of Natalia Romanova. A smoky cat-ish eye and nude lips should do it. I actually tried to make my eyelids look like shiny leather.
Too Faced Eyeshadow Primer
Inglot eyeshadows: black, white, silver, gold, light brown
Coastal Scents eyeshadows: Nude and orange
Urban Decay 24/7 liner Perversion
Lashes: Ardell 122
Lips: Dermosil Nude
Bad-assery: leather vest from Carlings
in the hopes of surviving finals...